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6. BioFabricating Materials

A collaborative works by Ruby Lennox, Maria-Rigina Chatzivalasi, Julija Karas, Hala Amer, and ChungHan Lu with mentorship from Petra and Julia.

Bioplastic a biobased polymer desived from a biomass. It is comprised of a biopolymer, plasticizer, and a solvent.
Polymer assemblies of identical chemical subunits, called monomers, that are linked together in the form of a chain.
Biobased Made of bacteria, fungi, mineral, vegetal, biosyntehtic, and animal.
Biodegradable Degrades in specific conditions like pH sensitive environments, thermo sensitive, and enzymes.
Biocompostable composted in 90 days like bacteria, mycelium, animals, etc.
Crafted Casted, extruded, and/or assembled.
Grown from scratch like fingii, microbial, and lab grown leathers.

What can Bioplastics be made of?

Plastics Bioplastics
Polymer Polymer Alginate, gelatine, starch, etc
Plasticizer to create flexibility glycerine (the more glycerine the more elastic but never exceed the 1:1 ration)
Filler to avoid shrinkage any waste like egg shells, chalk, fibers, oils, etc
Stiffening agent for structure and reinforcement fibers and natural debri, roots, plant matter
Expanding agent to create foams green soaps and emulsifiers (waste water of canned chickpeas could be used)

Plastics are usually made by mixing polymers with:

Biomaterials design properties are divided into structure, texture, color, and transparency.

You can make it magnetic by adding anything in the mixture that is magnet or magnetite. You can make it conductive by adding charcoal in it.

It matters what the sheets are casted on because it will adopt the textures and structures from the molds. For best results, cast agar agar and alginate on wood and textiles and gelatine on plastic moulds.

To play with the structural color of the cast, you can use defraction sheets.

Reference Projects

Alumni Inspiration!

Alumni projects that inspired me

BioFabricating Materials Notes

Tatami ReFAB Tatami ReFAB Repurposing and re-embeding tatami mats in modern life in Japan using 3D printing technology.
Algae Plastics Algae Plastics Using aquatic algae, drying them, and using them in material that can be 3D Printed.
Eduardo Loreto Heterotopia Screenprinting on lasercut carrot leather bag.

Standard Recipes

Sodium Alginate

"The sodium salt from alginic acid and gum mainly extracted from the cell walls of brown algae. Brown seaweeds are usually larfe, and range from the giant kelp that is often 20m long, to thick, leather-like seaweeds from 2 - 4m long, to smaller species 30 - 60cm long." (Credit Material Archive TextileLab Amsterdam)

Sodium Alginate Full Collage

Special Characteristics
Water Resistance Sodium Alginate becomes water proof! Will only dissolve in alkaline water.
Heat Resistance Withstands temperatures up to 150 degrees celsius.
Alginate Recipes // Global Lecture

Alginate Recipe Cecilia

Top two recipes will remain transparent even with pigments and the bottom will become matte.


Gelatine

Animal derived ingredient made from collagen present in animal parts.

Gelatine Full Collage

Special Characteristic:
Water Resistance Takes a couple of hours before dissolving in water.
Heat Resistance Not heat resistant at all. Begins melting at 50 degrees celsius.
Gelatine Recipes // Global Lecture

Recasting gelatine that has already cured makes more stable materials.

Gelatine Recipe Cecilia


Agar Agar

A jelly-like substance obtained from red algae. "Agar is a mixture of two components: the linear polysaccharide agarose, and a heterogenous mixture of smaller molecules called agaropectin. Agar is a compoind known as a polysaccharide." (Credit Material Archive TextileLab Amsterdam)

Agar Full Collage

Special Characteristic:
Water Resistance It dissolves in room temperature water in a few hours and hot water immediately.
Heat Resistance Not heat resistant. Best for short term use.
Agar Recipes // Global Lecture

Agar Recipe by Cecilia

Some tips, Agar can be casted in very thin films, resembling plastic foils. It can never be elastic but it is flexible. (Credit Material Archive TextileLab Amsterdam)


Resin

Resin Full Collage


Leather

Carrot Leather

Leather Full Collage

Banana Leather

Banana Leather Full Collage

Mushroom Leather

Mushroom Leather Full Collage


Mycelium

Mycelium Full Collage


Overview material research outcomes

Agar Agar // Stretch Foil

Agar Foil Test Using the stretch Bio-Foil recipe from the Global Lecture and pouring out a think layer.

main experimenter: Hala Amer

Agar Agar // Flexible Foil

Left to right stiff to flexible Using the flexible Bio-Foild recipe from the Global Lecture. Starting with no glycerol until 6g of glycerol (left to right).

main experimenter: Hala Amer

Agar agar // Glycerol

Based on recipe above, but in or to achieve "super elastic", add 48g Glycerol (initially elastic one 32g Glycerol), lay it on a flexible plastic sheet and try shaping it by rolling while it's partially dry.

main experimenter: ChungHan Lu

Agar agar // Glycerol

Based on recipe above, but in or to achieve "super elastic", added 48g Glycerol (initially elastic one 32g Glycerol), cast with the mold.

main experimenter: ChungHan Lu

Agar Agar // Sawdust // Pressed

Recipe above for Agar Agar with sawdust added. Spread in even layer with circular moulds placed on top and pushed in for whole drying process.

main experimenter: Ruby Lennox

Agar Agar // Eggshells

Agar Agar Foil recipe with Eggshells Letting the agar become more viscous before adding the eggshells into the mixture. Puring it on a circular wooden surface and allowing it to dry on it.

main experimenter: Hala Amer

Agar Agar // Foam

Agar Foam Whisking the regular agar recipe with soap to make a foam.

main experimenter: Hala Amer

Gelatin // Glycerol // Cabbage pigment

Recipe above(elstice one), added caggage pigment from Biochorme week. Unexpectedly, there were some burnt gelatin residues left at the bottom of the pot that got mixed into the new material during cooking. The dye's color isn't very pronounced, but these burnt gelatin substances added a new texture.

main experimenter: ChungHan Lu & Barbara Rakovská

Gelatin // Glycerol // Embedded Textile

Recipe above(elstice one), try to combining different materials, hoping that the external textile would interact with the gelatin bioplastic. Pour in the mold like a "sandwich": starting with one layer of material, then placing the textile, and finally adding another layer of material.

main experimenter: ChungHan Lu

Gelatin // Glycerol // Embedded Textile

Recipe above(elstice one), was useing the textile as the main material(structure), gelatin bioplastic as a coating, resulting in a thin, transparent layer on the textile.

main experimenter: ChungHan Lu

Gelatine // Foam // Flexible // Dye Bath

Gelatine Foam Purple Using a dye bath instead of regular water and making a flexible gelatine mixture. Once cooled down, its whisked to create a foam.

main experimenter: Hala Amer

Gelatine // Foam // Cabbage Dye Bath // Strings

Piped out like cake Using a dye bath instead of regular water and making a flexible gelatine mixture. Once cooled down, its whisked to create a foam.

Using less Glycerol, 10g to 400ml of water.

Using a plastic bag, pouring it out strings in shapes.

main experimenter: Hala Amer

Gelatine // Foam // Cabbage Dye Bath

In a bunch Using a dye bath instead of regular water and making a flexible gelatine mixture. Once cooled down, its whisked to create a foam.

Using less Glycerol, 10g to 400ml of water.

Pouring out a large blob. Resembles memory foam and goes back to shape in a few minutes.

main experimenter: Hala Amer

Gelatine // Foam // Rigid

For the expansion of the biomass, soap is added to the mixture. This experiment was conducted to see how well gelatine can foam without any additives.

main experimenter: Julija Karas

Gelatine // Foam // Soap // Rigid

Adding soap to the mixture creates a denser foam. The sample also bends while it is drying. That might have happened because no glycerol was added.

main experimenter: Julija Karas

Gelatine // Foam // Soap // Soft // Glycerol

Denser and softer sample as glycerol was added to the mixture.

main experimenter: Julija Karas

Gelatine // Foam // Soap // Soft // Glycerol

Whisking time of the biomass was longer which created an even denser and softer sample.

main experimenter: Julija Karas

Gelatine // Foam // Soap // Soft // Glycerol

Air was injected into the mixture after whisking and casting.

main experimenter: Julija Karas

Gelatine // Foam // Charcoal

Sample using the regular recipe above with added charcoal. Charcoal was injected using a syringe to create the patterns and bubbles.

main experimenter: Julija Karas

Gelatine // Foam // Charcoal

Lightweight rigid sample by casting it thin and not having glycerol.

main experimenter: Julija Karas

Gelatine // Foam // Charcoal

If a lot of charcoal is added to the mixture of biomass, the final material can be conductive. This was the first trial sample. Unfortunately, it is not conductive. Next step is to try with some metal powders instead.

main experimenter: Julija Karas

Gelatine // Foam // Wool

A sample mixing wool into the biofoam. An idea was to create a hard, thick, but light foam. Because of the thickness of the wet sample, the bottom side has not been able to dry properly and some of the wool fell out. No glycerol was added to the mix.

main experimenter: Julija Karas

Gelatine // Foam // Wool // Charcoal

A biofoam wool brick. Experimenting with different types and consistencies of materials used: biofoam, wool, and charcoal.

main experimenter: Julija Karas

Gelatine // Defraction

Regular gelatine mixture casted on a degraction film sheet to test the color structure.

main experimenter: Julija Karas

Alginate // Dye Bath // Woven

Recipe above for extruded alginate with dye bath from beetroot added for pink and from cabbage for blue strings. Woven while strings are wet.

main experimenter: Ruby Lennox

Alginate // Dye Bath // Knit

Recipe above for extruded alginate with dye bath from beetroot added. Knit while wet.

main experimenter: Ruby Lennox

Alginate // Charcoal // Knit

Recipe above for extruded alginate with charcoal added. Knit into chain while wet.

main experimenter: Ruby Lennox

Alginate // Sawdust

Recipe above for alginate mixed about 10:8 alginate to sawdust. Moulded around a glass while wet.

main experimenter: Ruby Lennox

Alginate // Sawdust // Layering

Recipe above for alginate. Layers or alginate in different shapes covered in sawdust between each layer then sprayed with calcium chloride.

main experimenter: Ruby Lennox

Alginate // Molded

Recipe above for alginate painted in a very thin layer then sprayed with calcium chloride and reshaped while gelling.

main experimenter: Ruby Lennox

Alginate // Layering

Recipe above for alginate. Multiple layers poured over a bowl mould with calcium chloride spared in between each layer.

main experimenter: Ruby Lennox

Alginate // Foam // Charcoal

Alginate Black Foam Adding charcoal to the sodium alginate mixture. After allowing it to cool, whisking it to make foam.

main experimenter: Hala Amer & Julija Karas

Alginate // Foam // Spirulina

Alginate Foam with Spirulina Adding spirulina to the sodium alginate mixture. After allowing it to cool, whisking it to make foam. Once casted, a lasercut pattern is placed on top to get the shape.

main experimenter: Hala Amer & Julija Karas

Leather // Carrot // Sodium Alginate

Carrot Bioleather with sodium alginate Recipe above. Chopped carrots with sodium alginate mixture with glycerol for flexibility.

main experimenter: Hala Amer

Pine resin // Carnauba wax // Alcohol // Saw dust

Recipe above, but would like to keep more translucency, so added less filler.

main experimenter: all

Potential Research

Date Palm Trees.

As this is my first time reading about biomaterials and working with them I happened to notice the use of Oil Palm and was intrigues in whether the Date Palm Tree has been experimented with. I found a number of scientific research papers stating that the Date Palm Tree has lots of potential to be used and has a lot of waste in the life cycle of the tree.

Unveiling the Biocompatible Properties of Date Palm Tree (Phoenix dactylifera L.) Biomass-Derived Lignin Nanoparticles

Date Palm Tree Waste Recycling: Treatment and Processing for Potential Engineering Applications

"It takes around six years for date palms to bear fruit after planting and around nine years to produce viable yields for commercial harvest. Usually, date palm wastes are burned on farms or disposed in landfills, which cause environmental pollution in date-producing nations. In addition, date palm has a high volatile solid content and low moisture content. These factors make date palm residues an excellent biomass resource in date-palm producing nations."

Schematic of Date Palm Tree

"The offshoot should be removed, and dead or defective fronds need to be removed yearly, which generates about 20 kg of waste per year from only one date palm. Some studies have reported that Saudi Arabia alone generates more than 200,000 tons of date palm biomass each year. The date palm wastes are in the form of fronds, offshoots, dried fronds base (karab), and date pits. According to local farmers, they usually collect this waste and burn it. A small fraction of the waste is shredded and blended with other bio waste to be used as animal feed, or leaved aside to break down naturally to be used as fertilizer."

Weight Percentage

Physical Properties

Biomass Analysis

Tensile Strength

Cellulose nanocrystal extracted from date palm fibre: Morphological, structural and thermal properties

"However, the improper handling of underutilized date palm bunch stalk after harvest season has resulted in the biomass waste disposal problem. Generally, the bunch stalk part of date palm contains 44.0 % cellulose, 26.0 % hemicellulose, and 11.5 % lignin, and the rest of 18.5 % other compounds. Therefore, the environmental concern can be reduced by deriving its cellulose-riched date palm bunch stalk into nanocellulose product.

Celllose nanocrystal (CNC), a nano-sized particle from plant biomass, is a promising bio-filling agent that often used in polymer reinforcement application. From the aspect of feature, CNC is a rod-like elementary crystals with its intact crystalline feature.

Effects of Replacing Cement by Date Palm Trees Wastes on Concrete Performance

"The results showed that palm leaves ash enhanced concrete workability and concrete compressive strength."

Cement

Ecofriendly Dyeing of Textile Materials with Natural Colorants from Date Palm Fiber Fibrillium

Ground

"The fibrillium material was collected in December 2021 in the Gabes region, a city in southeastern Tunisia with an oasis of hundreds of thousands of palm trees. Samples are finely chopped to remove decomposed parts and washed with water to remove dirt and dust. They were then dried and finely ground into a powder. A multi-fiber fabric consisting of different fibers and containing fabric strips (acetate, cotton, nylon, polyester, acrylic, and wool) was used for testing affinity. 100% washed and bleached wool fabrics (200 g/m2) and bleached polyamide knit fabrics (150 g/m2) have been used to investigate the overall dyeing parameters. Alum, ferrous sulfate and tannic acid were laboratory reagents grade and were used without further purification. Commercial Mimosa extract was obtained from Silvateam. In the current study, 50 g of ground date palm plant was boiled for 1 h in 1 L of distilled water. The resulting solution was then filtered to remove plant debris and used for dyeing."

Dyeing Affinity

References